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It's likely to be entertaining on Tuesday night at the Estadio de La Cerámica. Villarreal may only have three points so far, but they have given almost as good as they have got. They were beaten late on in Dortmund (3-2) before losing a seven-goal thriller in Liverpool two weeks ago. In between those encounters, they took their first win with a 3-1 defeat of Napoli and are now looking for a second successive home win.
Paris Saint-Germain have been impressive so far though. After seeing off Slovan Bratislava (6-1) and Manchester City (4-2), the double European champions then defeated Barcelona (4-2) to make it three wins from three in this season's league phase. They head to Spain aiming to extend that 100% record.