Identifying the most educated football players in South Africa can be challenging as detailed information about the educational backgrounds of players is not always publicly available. However, there are some notable players who have pursued higher education alongside their football careers. Here are a few examples:

1. Siyabonga Nomvethe: Siyabonga Nomvethe, a retired South African striker, is known for his dedication to education. He earned a degree in Sports Management from the University of South Africa (UNISA) while playing professional football.

2. Daine Klate: Daine Klate, a former South African winger, completed his Bachelor's degree in Marketing at the Nelson Mandela Metropolitan University (NMMU) in Port Elizabeth.

3. Tsepo Masilela: Tsepo Masilela, a former South African left-back, studied towards a degree in Sports Science at the University of Pretoria.

4. Siphiwe Tshabalala: Siphiwe Tshabalala, a former South African midfielder, pursued his studies in Information Technology at Vaal University of Technology.

5. Itumeleng Khune: Itumeleng Khune, a goalkeeper for Kaizer Chiefs and the South African national team, has shown an interest in furthering his education but specific details about his academic pursuits are not widely known.

Please note that the educational achievements of football players can vary, and the above examples are just a few instances of players who have pursued higher education alongside their football careers in South Africa.

Sources:

https://www.newshub360.net/south-african-footballers-with-university-degrees/

https://www.google.com/amp/s/www.snl24.com/amp/kickoff/lifestyle/star-style/percy-tau-among-8-south-african-football-stars-who-obtained-degrees-20200513

https://www.sarichandfamous.com/2020/05/29/watch-psl-players-who-are-educated-and-have-degrees/

https://www.snl24.com/dailysun/sport/meet-academically-educated-psl-players-20210217

https://www.snl24.com/kickoff/lifestyle/star-style/percy-tau-among-8-south-african-football-stars-who-obtained-degrees-20200513

https://www.newshub360.net/south-african-footballers-with-university-degrees/